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1.
A. P. Vink E. van der Kolk P. Dorenbos C. W. E. van Eijk 《Optics Communications》2002,210(3-6):277-284
The optical properties of Ce3+ in CaSO4, SrSO4 and BaSO4 are reported. The Ce3+ ion shows 4f05d1→2F5/2,2F7/2 luminescence in all three sulphates. Co-doping with Na+ does not change the local surrounding of the Ce3+ ion, but enhances the amount of Ce3+ ions built in. Under optical excitation, besides the typical Ce3+ doublet emission in the ultraviolet spectral region, band emission around 445 nm was observed. This band emission was not assigned to emission from a Ce3+ centre, but to emission from an impurity-trapped exciton. Under X-ray excitation, both Ce3+ emission and an emission band around 380 nm was observed. This band was assigned to emission from a self-trapped exciton. 相似文献
2.
通过系统研究A~190区超形变核中转动带的转动惯量、角动量顺排、旋称分裂随转动频率的变化规律, 结合我们用处理对力的粒子数守恒方法的计算结果, 对A~190区所有转动带的组态结构给出了一个整体的描述. 绝大多数超形变带都建立在强耦合轨道上, 例如中子[512]5/2, [624]9/2. 少数超形变带则建立在高j闯入轨道上, 即中子[761]3/2, [752]5/2. 根据我们提出的组态结构所进行的理论计算结果表明, A~190区所有转动带的一般行为、反常变化和带交叉都得到了满意的解释. 相似文献
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在利用Harris两参数公式研究Bohr-Mottelson转动谱公式参数之间的关系的基础上,改用Harris三参数公式,并由此提出了Bohr-Mottelson转动谱公式参数之间的新关系式,进而用I(I+1)四参数展开式计算了A~60,80,130,140,150,190区超形变偶偶核的基带和锕系和稀土区正常形变核基带,讨论了参数之间的关系,发现新关系式与实验较好地符合. 相似文献
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Ahilleas N. Maurellis Rüdiger Lang Jochen Landgraf 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,84(3):295-323
The computation of radiation transmittance in nongray, inhomogeneous atmospheric models is frequently complicated by complex bands of line spectra which range in value over many orders of magnitudes and depend strongly on either or both of pressure and temperature. We present here a new opacity sampling technique which is shown to determine correctly the wavelength-averaged extinction due to path-dependent realizations of banded line spectra. The technique is easy to implement computationally and is applicable to a wide variety of atmospheric problems in which frequent iteration of the radiative transfer model is required. We consider two such instances: modeling of solar flux attenuation for use in a time-dependent planetary ionosphere model and retrieval from nadir measurements of backscattered solar irradiance. The power of the new method lies in its straightforward analytical treatment of both atmospheric inhomogeneity and spectral complexity. It is thus relevant for both retrieval and radiative transfer modeling purposes. 相似文献
9.
Precipitate-forming chemical reactions have been studied in chemically cross-linked poly(vinyl alcohol) gel medium. One of the reactive components was incorporated into the gel, the other was allowed to diffuse into it. Depending on the experimental conditions the reaction-diffusion process often results in patterns of different type. Experiments performed in tubes and in thin layers were carried out in order to investigate the effects of various factors (cross-linking density, swelling degree as well as the concentrations of the outer and inner electrolytes) on the morphologies of the precipitate patterns. It was found that precipitation occurs not only in the Liesegang bands, but also between bands. Beside Liesegang-type structures, tree-like patterns have been observed, showing a characteristic periodicity in the density profile obtained by digitalized image analyses. 相似文献
10.
The mid-infrared (1500-3800 cm−1) absorption spectrum of gaseous nitric oxide has been studied at low temperature (99 K) with a long absorption path (160 m) in order to observe weak combination, difference, and overtone bands of the NO dimer. About ten new bands were assigned with greater or lesser certainty. Combined with previous results, they lead to a set of 12 secure and 7 tentative vibrational term values for (NO)2, essentially doubling our knowledge of NO dimer vibrational states. The strongest non-fundamental bands in this region, other than the ν1 (symmetric N-O stretch) + ν5 (asymmetric N-O stretch) overtone, involve combinations of ν5 with ν3 (intermolecular stretch). Excitation of ν5 results in increased frequencies for the intermolecular modes ν2, ν3, and ν4. A new value of 155.5 cm−1 was obtained for ν4, the elusive infrared-inactive out-of-plane fundamental vibration. 相似文献